Defeat Glenn in the Chroma League Champion Battle and watch the ending credits. Mia will tell you about a secret league named the "Iron League". Enter it to face the Top 8 trainers and battle the Grand Master.
Hold L + R + Down and press Start at the title screen. All characters and support Pokemon will be available in this mode.
On the title screen, hold down L, R and Down on the D-Pad and press Start.
Scan up to five different Amiibos at the main menu map screen to get a Lucky Bonus. This can be done once per day, after midnight. Note: The Shadow Mewtwo card will not count the first time it is scanned.
After your Partner Pokemon reach certain Skill Levels, Ribbons will appear on their pictures when you look at the Details in the Menu, your information in My Town, and on their icons in the Character Select Screen.
Have your Partner Pokemon reach the indicated skill levels to have the corresponding color ribbon appear on their portrait images at various menus.
Complete the indicated task to unlock the corresponding Pokemon.
Complete the indicated task to unlock the corresponding stage.
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Complete the indicated task to unlock the corresponding Pokemon.